Spider-Man (1994)

S02E01 Neogenic Nightmare: The Insidious Six

Silvermane, at the helm of the Crime Lords, confronts the Kingpin about his inability to dispose of Spider-Man. In response, he assembles a formidable team of the web-slinger’s most notorious foes: Doctor Octopus, Mysterio, the Scorpion, the Rhino, the Shocker, and the Chameleon. However, Spider-Man finds himself at a disadvantage, as his abilities are faltering due to recent alterations in his blood chemistry.